Issue 45, 2013
From the journal:

Dalton Transactions

Programmed functionalization of SURMOFs via liquid phase heteroepitaxial growth and post-synthetic modification†

Min Tu,a   Suttipong Wannapaiboona  and  Roland A. Fischer*a  

* Corresponding authors

a Chair of Inorganic Chemistry II – Organometallics and Materials Chemistry, Ruhr Universität Bochum, D-44780 Bochum, Germany
E-mail: roland.fischer@rub.de
Fax: +49 (0) 234 32-14174
Tel: +49 (0) 234 32-23629

Abstract

Heterostructured surface mounted metal–organic frameworks (SURMOFs) [Cu2(NH2-bdc)2(dabco)] (B) on top of [Cu2(bdc)2(dabco)] (A) were deposited on pyridyl-terminated Au covered QCM substrate using a step-by-step liquid phase epitaxial growth method. Sequentially, the pore size of the top layer [Cu2(NH2-bdc)2(dabco)] (B) was modified by targeting the installed amino moiety with tert-butyl isothiocyanate (tBITC). The adsorption properties of the programmed functionalized SURMOFs studied using an environment controlled quartz crystal microbalance (QCM) instrument exhibited the possibility to achieve high selectivity and capacity by heteroepitaxial growth and post-synthetic modification.

Graphical abstract: Programmed functionalization of SURMOFs via liquid phase heteroepitaxial growth and post-synthetic modification

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Article information

DOI
https://doi.org/10.1039/C3DT51457A
Article type
Paper
Submitted
03 Jun 2013
Accepted
18 Jul 2013
First published
19 Jul 2013

Dalton Trans., 2013,42, 16029-16035

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Programmed functionalization of SURMOFs via liquid phase heteroepitaxial growth and post-synthetic modification

M. Tu, S. Wannapaiboon and R. A. Fischer, Dalton Trans., 2013, 42, 16029 DOI: 10.1039/C3DT51457A

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