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Issue 47, 2013
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Towards a self-assembled honeycomb structure via diaminotriptycene metal complexes

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Abstract

We illustrate a new approach toward the synthesis of a porous supramolecular honeycomb based on triptycene. A coordination polymer has been prepared where the triptycene groups are linked through triptycenesemiquinonediimine platinum complexes, but the product is disordered rather than the intended honeycomb structure. A model platinum complex and its 15N-labeled isotopomer have been prepared and characterized.

Graphical abstract: Towards a self-assembled honeycomb structure via diaminotriptycene metal complexes

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Article information


Submitted
21 May 2013
Accepted
02 Oct 2013
First published
16 Oct 2013

Dalton Trans., 2013,42, 16474-16477
Article type
Communication

Towards a self-assembled honeycomb structure via diaminotriptycene metal complexes

Q. Liang, J. H. Chong, N. G. White, Z. Zhao and M. J. MacLachlan, Dalton Trans., 2013, 42, 16474
DOI: 10.1039/C3DT51330K

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