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Issue 47, 2013
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Towards a self-assembled honeycomb structure via diaminotriptycene metal complexes

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Abstract

We illustrate a new approach toward the synthesis of a porous supramolecular honeycomb based on triptycene. A coordination polymer has been prepared where the triptycene groups are linked through triptycenesemiquinonediimine platinum complexes, but the product is disordered rather than the intended honeycomb structure. A model platinum complex and its 15N-labeled isotopomer have been prepared and characterized.

Graphical abstract: Towards a self-assembled honeycomb structure via diaminotriptycene metal complexes

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Publication details

The article was received on 21 May 2013, accepted on 02 Oct 2013 and first published on 16 Oct 2013


Article type: Communication
DOI: 10.1039/C3DT51330K
Citation: Dalton Trans., 2013,42, 16474-16477
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    Towards a self-assembled honeycomb structure via diaminotriptycene metal complexes

    Q. Liang, J. H. Chong, N. G. White, Z. Zhao and M. J. MacLachlan, Dalton Trans., 2013, 42, 16474
    DOI: 10.1039/C3DT51330K

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