Issue 33, 2013
From the journal:

Dalton Transactions

A half-sandwich 1,2-azaborolyl ruthenium complex: synthesis, characterization, and evaluation of its catalytic activities†

Zicheng Liu,a   Junjie Xu,a   Wenqing Ruan,a   Chen Fu,a   Hui-Jun Zhanga  and  Ting-Bin Wen*a  

* Corresponding authors

a Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, People's Republic of China
E-mail: chwtb@xmu.edu.cn
Fax: (+86) 592-218-6295
Tel: (+86) 592-218-6085

Abstract

A half-sandwich 1,2-azaborolyl (Ab) ruthenium complex, (Ab–C[triple bond, length as m-dash]CPh)RuCl(PPh3)2 (1), has been synthesized by treating RuCl2(PPh3)3 with lithium 1,2-azaborolide L-1, or by treating either RuCl2(PPh3)3 or RuHCl(PPh3)3 directly with 1,2-azaborole LH-1. It is evaluated as a suitable precatalyst in [2 + 2] cycloadditions of norbornene derivatives with DMAD and in atom transfer radical additions of halogenated compounds with olefins.

Graphical abstract: A half-sandwich 1,2-azaborolyl ruthenium complex: synthesis, characterization, and evaluation of its catalytic activities

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3DT51177D
Article type
Communication
Submitted
05 May 2013
Accepted
24 Jun 2013
First published
25 Jun 2013

Dalton Trans., 2013,42, 11976-11980

Permissions

Request permissions

A half-sandwich 1,2-azaborolyl ruthenium complex: synthesis, characterization, and evaluation of its catalytic activities

Z. Liu, J. Xu, W. Ruan, C. Fu, H. Zhang and T. Wen, Dalton Trans., 2013, 42, 11976 DOI: 10.1039/C3DT51177D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements