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Issue 32, 2013
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Abnormal carbenes derived from the 1,5-cycloaddition product between azides and alkynes: structural characterization of Pd(ii) complexes and their catalytic properties

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Abstract

The exclusive formation of the 1,5-cycloaddition product between azides and alkynes is taken advantage of in generating the first examples of abnormal carbenes from these precursors. This new route provides unprecedented post-functionalization possibilities for such abnormal carbenes.

Graphical abstract: Abnormal carbenes derived from the 1,5-cycloaddition product between azides and alkynes: structural characterization of Pd(ii) complexes and their catalytic properties

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Article information


Submitted
25 Apr 2013
Accepted
14 May 2013
First published
14 May 2013

Dalton Trans., 2013,42, 11355-11358
Article type
Communication

Abnormal carbenes derived from the 1,5-cycloaddition product between azides and alkynes: structural characterization of Pd(II) complexes and their catalytic properties

S. Hohloch, W. Frey, C. Su and B. Sarkar, Dalton Trans., 2013, 42, 11355
DOI: 10.1039/C3DT51083B

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