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Issue 16, 2013
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Iron-mediated C–H bond amination by organic azides on a tripodal bis(anilido)iminophosphorane platform

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Abstract

The bis(anilido)iminophosphorane complex, abbreviated as [(MesN2NAd)Fe(THF)], can react with alkyl azides to yield ligand-based C–H bond amination products suggesting the high reactivity of iron(IV)–imido species supported by the tripodal bis(anilido)iminophosphorane ligand platform [MesN2NAd]2−.

Graphical abstract: Iron-mediated C–H bond amination by organic azides on a tripodal bis(anilido)iminophosphorane platform

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Article information


Submitted
22 Feb 2013
Accepted
26 Feb 2013
First published
26 Feb 2013

Dalton Trans., 2013,42, 5607-5610
Article type
Communication

Iron-mediated C–H bond amination by organic azides on a tripodal bis(anilido)iminophosphorane platform

J. Xiao and L. Deng, Dalton Trans., 2013, 42, 5607
DOI: 10.1039/C3DT50518A

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