Issue 25, 2013
From the journal:

Dalton Transactions

Regio- and stereospecific living polymerization and copolymerization of (E)-1,3-pentadiene with 1,3-butadiene by half-sandwich scandium catalysts†

Kei Nishii,ab   Xiaohui Kang,ac   Masayoshi Nishiura,a   Yi Luoc  and  Zhaomin Hou*ac  

* Corresponding authors

a Organometallic Chemistry Laboratory and Advanced Catalyst Research Team, RIKEN Advanced Science Institute, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan
E-mail: houz@riken.jp
Fax: +81 48 462 4665
Tel: +81 48 467 9393

b Department of Materials Chemistry and Bioengineering, Oyama National College of Technology, 771 Nakakuki, Oyama, Tochigi 323-0806, Japan

c State Key Laboratory of Fine Chemicals, School of Pharmaceutical Science and Technology, Dalian University of Technology, Dalian 116024, China

Abstract

The living isospecific-cis-1,4-polymerization and block-copolymerization of (E)-1,3-pentadiene with 1,3-butadiene have been achieved for the first time by using cationic half-sandwich scandium catalysts.

Graphical abstract: Regio- and stereospecific living polymerization and copolymerization of (E)-1,3-pentadiene with 1,3-butadiene by half-sandwich scandium catalysts

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Article information

DOI
https://doi.org/10.1039/C3DT50357G
Article type
Communication
Submitted
05 Feb 2013
Accepted
04 Mar 2013
First published
04 Mar 2013

Dalton Trans., 2013,42, 9030-9032

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Regio- and stereospecific living polymerization and copolymerization of (E)-1,3-pentadiene with 1,3-butadiene by half-sandwich scandium catalysts

K. Nishii, X. Kang, M. Nishiura, Y. Luo and Z. Hou, Dalton Trans., 2013, 42, 9030 DOI: 10.1039/C3DT50357G

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