Spins on a curved surface: an FeIII14 ferracalixarene†
Abstract
The synthesis of the high-nuclearity FeIII14 coordination cluster [Fe14(μ3-O)6(μ3-OH)4(μ-OH)3Cl11(dea)4(Hdea)3]Cl·H2O·27MeCN (1) is reported (in which deaH2 =
* Corresponding authors
a
Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesserstr. 15, D-76131 Karlsruhe, Germany
E-mail:
annie.powell@kit.edu, manase.ayuk@kit.edu
Fax: +49-721-608-48142
Tel: +49-721-608-42135
b Institute of Nanotechnology, Karlsruhe Institute of Technology, Postfach 3640, D-76021 Karlsruhe, Germany
c Departament de Química Inorgànica and Institut de Recerca de Química Teòrica i Computacional, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain
The synthesis of the high-nuclearity FeIII14 coordination cluster [Fe14(μ3-O)6(μ3-OH)4(μ-OH)3Cl11(dea)4(Hdea)3]Cl·H2O·27MeCN (1) is reported (in which deaH2 =
A. M. Ako, Y. Lan, V. Mereacre, E. Ruiz, D. Aravena, C. E. Anson and A. K. Powell, Dalton Trans., 2013, 42, 9606 DOI: 10.1039/C3DT50345C
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