Issue 25, 2013
From the journal:

Dalton Transactions

Uranium(iv) amido-borohydrides as highly active diene polymerisation catalysts†‡

Stephen M. Mansell,a   Fanny Bonnet,*b   Marc Visseaux*b  and  Polly L. Arnold*a  

* Corresponding authors

a EaStCHEM School of Chemistry, University of Edinburgh, Joseph Black Building, The King's Buildings, Edinburgh, EH9 3JJ, UK
E-mail: polly.arnold@ed.ac.uk

b CNRS, UMR8181, ENSCL, UCCS, CCM, F-59652 Villeneuve d'Ascq, Univ. Lille Nord de France, F-5900 Lille, France

Abstract

The synthesis and structural characterisation of the uranium(IV) amido-borohydrides (N′′)2U{κ2-N(SiMe3)SiMe2CH2BBN-H} and U{κ2-N(SiMe3)SiMe2CH2BBN-H}2, and their activity as pre-catalysts for the polymerisation of isoprene are described.

Graphical abstract: Uranium(iv) amido-borohydrides as highly active diene polymerisation catalysts

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Article information

DOI
https://doi.org/10.1039/C3DT50131K
Article type
Paper
Submitted
14 Jan 2013
Accepted
22 Mar 2013
First published
10 Apr 2013

Dalton Trans., 2013,42, 9033-9039

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Uranium(IV) amido-borohydrides as highly active diene polymerisation catalysts

S. M. Mansell, F. Bonnet, M. Visseaux and P. L. Arnold, Dalton Trans., 2013, 42, 9033 DOI: 10.1039/C3DT50131K

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