The first heterometallic examples of 3d–4f heptanuclear [MnII3LnIII4] complexes with planar disc-like cores and diverse magnetic properties

Jinying Liu; Chengbing Ma; Hui Chen; Mingqiang Hu; Huimin Wen; Honghua Cui; Changneng Chen

doi:10.1039/C3DT32985B

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The first heterometallic examples of 3d–4f heptanuclear [Mn^II₃Ln^III₄] complexes with planar disc-like cores and diverse magnetic properties†

Jinying Liu,^ab Chengbing Ma,*^a Hui Chen,^a Mingqiang Hu,^a Huimin Wen,^a Honghua Cui^ab and Changneng Chen*^a

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* Corresponding authors

^a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
E-mail: ccn@fjirsm.ac.cn
Fax: +86 591 83792395

^b Graduate School of the Chinese Academy of Sciences, Beijing 100039, China

Abstract

A family of heptanuclear [Mn^II₃Ln^III₄] clusters with planar disc-like cores have been synthesized by a solvothermal route, where Ln = La, Pr, Nd, and Gd, and such fascinating topology is unprecedented in 3d–4f complexes. Dc magnetic susceptibility data show different magnetic behaviors derived from the difference in Ln ions.

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Article information

DOI: https://doi.org/10.1039/C3DT32985B
Article type: Communication
Submitted: 12 Dec 2012
Accepted: 15 Jan 2013
First published: 07 Feb 2013

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Dalton Trans., 2013,42, 3787-3790

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The first heterometallic examples of 3d–4f heptanuclear [Mn^II₃Ln^III₄] complexes with planar disc-like cores and diverse magnetic properties

J. Liu, C. Ma, H. Chen, M. Hu, H. Wen, H. Cui and C. Chen, Dalton Trans., 2013, 42, 3787 DOI: 10.1039/C3DT32985B

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