Jump to main content
Jump to site search

Issue 14, 2013
Previous Article Next Article

Cycloaddition reactions between dicyclohexylboron azide and alkynes

Author affiliations

Abstract

The room temperature 1,3-dipolar cycloaddition reactions of the boron azide, Cy2BN3 with the electron-poor acetylenes RCO2C[triple bond, length as m-dash]CCO2R, EtC[triple bond, length as m-dash]CCOMe and HC[triple bond, length as m-dash]CP([double bond, length as m-dash]O)Ph2 afforded new 1,2,3-triazoles. In the case of RCO2C[triple bond, length as m-dash]CCO2R, a new macrocyclic product was isolated with loss of the R group.

Graphical abstract: Cycloaddition reactions between dicyclohexylboron azide and alkynes

Back to tab navigation

Supplementary files

Publication details

The article was received on 08 Jan 2013, accepted on 11 Feb 2013 and first published on 22 Feb 2013


Article type: Communication
DOI: 10.1039/C3DT00068K
Citation: Dalton Trans., 2013,42, 4795-4798
  •   Request permissions

    Cycloaddition reactions between dicyclohexylboron azide and alkynes

    R. L. Melen and D. W. Stephan, Dalton Trans., 2013, 42, 4795
    DOI: 10.1039/C3DT00068K

Search articles by author

Spotlight

Advertisements