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Issue 10, 2013
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Hydrophosphination of vinyl-boranes with phosphinoamines

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Abstract

Phosphinoamine ligands PhN(H)PR2 (R = iPr 1, tBu 2) react with R1CH[double bond, length as m-dash]CR2B(C6F5)2 (R1 = Ph, p-FC6H4, nPr, Et, R2 = H, Ph, Et, C6F5) to effect uncatalyzed hydrophosphination of the olefinic bond, affording the C2BNP five-membered cyclization compounds 3–14. All the compounds are fully characterized and compounds 4, 7, 8 and 9 are studied by X-ray diffraction analysis.

Graphical abstract: Hydrophosphination of vinyl-boranes with phosphinoamines

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Publication details

The article was received on 09 Nov 2012, accepted on 11 Dec 2012 and first published on 04 Jan 2013


Article type: Paper
DOI: 10.1039/C2DT32677A
Citation: Dalton Trans., 2013,42, 3318-3325
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    Hydrophosphination of vinyl-boranes with phosphinoamines

    C. Jiang and D. W. Stephan, Dalton Trans., 2013, 42, 3318
    DOI: 10.1039/C2DT32677A

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