Issue 12, 2013
From the journal:

Dalton Transactions

Hydrothermal synthesis of an ortho-metallated Co(iii) complex anchored by a carboxylate group with a selective oxidation catalytic property†

Shi-Yuan Zhang,a   Wei Shi,*a   Jian-Gong Ma,a   Yu-Qi Zhang,a   Zhen-Jie Zhanga  and  Peng Cheng*a  

* Corresponding authors

a Department of Chemistry and Key Laboratory of Advanced Energy Materials Chemistry (MOE), TKL of Metal and Molecule Based Material Chemistry, Nankai University, Tianjin 300071, P. R. China
E-mail: shiwei@nankai.edu.cn
Fax: +86-022-23502458
Tel: +86-022-23503059

Abstract

An air-stable and water-tolerant ortho-metallated complex [Co(tfb)(bpy)2](NO3)·3H2O was obtained via hydrothermal synthesis. The mechanism for the formation of Co–C bond was studied using both DFT calculations and experimental analysis. This highly stable complex exhibits good catalytic performance for the selective oxidation of cyclohexane.

Graphical abstract: Hydrothermal synthesis of an ortho-metallated Co(iii) complex anchored by a carboxylate group with a selective oxidation catalytic property

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Article information

DOI
https://doi.org/10.1039/C2DT32468G
Article type
Paper
Submitted
17 Oct 2012
Accepted
17 Dec 2012
First published
17 Dec 2012

Dalton Trans., 2013,42, 4313-4318

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Hydrothermal synthesis of an ortho-metallated Co(III) complex anchored by a carboxylate group with a selective oxidation catalytic property

S. Zhang, W. Shi, J. Ma, Y. Zhang, Z. Zhang and P. Cheng, Dalton Trans., 2013, 42, 4313 DOI: 10.1039/C2DT32468G

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