Issue 33, 2013
From the journal:

Dalton Transactions

Vanadium-catalyzed enantioselective Friedel–Crafts-type reactions†

Shinobu Takizawa,a   Fernando Arteaga Arteaga,a   Yasushi Yoshida,a   Junpei Kodera,a   Yoshihiro Nagataa  and  Hiroaki Sasai*a  

* Corresponding authors

a The Institute of Scientific and Industrial Research (ISIR), Osaka University, Mihogaoka, Ibaraki-shi, Osaka 567-0047, Japan
E-mail: sasai@sanken.osaka-u.ac.jp
Fax: +81 6 6879 8465
Tel: +81 6 6879 8469

Abstract

Vanadium-mediated enantioselective Friedel–Crafts (FC)-type reactions were established using the dinuclear vanadium complex (Ra,S,S)-1a. The vanadium complex promoted the FC-type reaction of imines with 2-naphthols or indoles to give corresponding adducts with high enantioselectivities.

Graphical abstract: Vanadium-catalyzed enantioselective Friedel–Crafts-type reactions

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Article information

DOI
https://doi.org/10.1039/C2DT32202A
Article type
Communication
Submitted
21 Sep 2012
Accepted
08 Oct 2012
First published
10 Oct 2012

Dalton Trans., 2013,42, 11787-11790

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Vanadium-catalyzed enantioselective Friedel–Crafts-type reactions

S. Takizawa, F. A. Arteaga, Y. Yoshida, J. Kodera, Y. Nagata and H. Sasai, Dalton Trans., 2013, 42, 11787 DOI: 10.1039/C2DT32202A

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