Issue 11, 2013
From the journal:

Catalysis Science & Technology

A silver-free system for the direct C–H auration of arenes and heteroarenes from gold chloride complexes†

Nanna Ahlsten,a   Gregory J. P. Perry,a   Xacobe C. Cambeiro,a   Tanya C. Boormana  and  Igor Larrosa*a  

* Corresponding authors

a School of Biological and Chemical Sciences, Queen Mary University of London, Joseph Priestley Building, Mile End Road, London, UK
E-mail: i.larrosa@qmul.ac.uk
Web: http://webspace.qmul.ac.uk/ilarrosa/index.html

Abstract

A new methodology for the direct C–H auration of electron-deficient arenes and heteroarenes with simple bases and readily available [Au(PR3)Cl] complexes is described. This system allows the preparation of a wide scope of aryl–Au(I) compounds without the need for using Ag(I) additives or preparing and isolating basic Au(I) hydroxide complexes.

Graphical abstract: A silver-free system for the direct C–H auration of arenes and heteroarenes from gold chloride complexes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CY00240C
Article type
Communication
Submitted
12 Apr 2013
Accepted
13 Jun 2013
First published
14 Jun 2013
This article is Open Access
Creative Commons BY license

Catal. Sci. Technol., 2013,3, 2892-2897

Permissions

Request permissions

A silver-free system for the direct C–H auration of arenes and heteroarenes from gold chloride complexes

N. Ahlsten, G. J. P. Perry, X. C. Cambeiro, T. C. Boorman and I. Larrosa, Catal. Sci. Technol., 2013, 3, 2892 DOI: 10.1039/C3CY00240C

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements