Issue 3, 2013
From the journal:

Catalysis Science & Technology

Secondary phosphineoxides as pre-ligands for nanoparticle stabilization†

Eoin Rafter,a   Torsten Gutmann,bc   Florian Löw,d   Gerd Buntkowsky,e   Karine Philippot,bc   Bruno Chaudretf  and  Piet W. N. M. van Leeuwen*a  

* Corresponding authors

a Institute of Chemical Research of Catalonia (ICIQ), 43007 Tarragona, Spain
E-mail: pvanleeuwen@iciq.es
Fax: +34 977 920 221

b CNRS, LCC (Laboratoire de Chimie de Coordination), 205, Route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France

c Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France

d Institute of Physical Chemistry, Technical University Darmstadt, Petersenstrasse 22, D-64287 Darmstadt, Germany

e Institute for Condensed Matter Physics, Technical University Darmstadt, Hochschulstraße 6, D-64289 Darmstadt, Germany

f Université de Toulouse, INSA, UPS, CNRS, LPCNO, 135 Avenue de Rangueil, F-31077 Toulouse, France

Abstract

The synthesis of ruthenium nanoparticles (RuNPs) using secondary phosphine oxides (SPOs) as ligands is reported. These easily accessible ligands allow the formation of small nanoparticles in the size range of 1–2 nm which display a high efficiency for hydrogenation of aromatics with TOFs up to 2700 mol h−1.

Graphical abstract: Secondary phosphine oxides as pre-ligands for nanoparticle stabilization

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CY20683H
Article type
Paper
Submitted
04 Oct 2012
Accepted
21 Nov 2012
First published
12 Dec 2012

Catal. Sci. Technol., 2013,3, 595-599

Permissions

Request permissions

Secondary phosphine oxides as pre-ligands for nanoparticle stabilization

E. Rafter, T. Gutmann, F. Löw, G. Buntkowsky, K. Philippot, B. Chaudret and P. W. N. M. van Leeuwen, Catal. Sci. Technol., 2013, 3, 595 DOI: 10.1039/C2CY20683H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements