Supramolecular H-bonded porous networks at surfaces: exploiting primary and secondary interactions in a bi-component melamine–xanthine system

Artur Ciesielski; Sébastien Haar; Gábor Paragi; Zoltán Kupihár; Zoltán Kele; Stefano Masiero; Célia Fonseca Guerra; F. Matthias Bickelhaupt; Gian Piero Spada; Lajos Kovács; Paolo Samorì

doi:10.1039/C3CP50891A

Supramolecular H-bonded porous networks at surfaces: exploiting primary and secondary interactions in a bi-component melamine–xanthine system†‡

Artur Ciesielski,^a Sébastien Haar,^a Gábor Paragi,^b Zoltán Kupihár,^c Zoltán Kele,^c Stefano Masiero,^d Célia Fonseca Guerra,^e F. Matthias Bickelhaupt,^ef Gian Piero Spada,^d Lajos Kovács*^c and Paolo Samorì*^a

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* Corresponding authors

^a Nanochemistry Laboratory, ISIS & icFRC, Université de Strasbourg & CNRS, 8 allée Gaspard Monge, Strasbourg, France
E-mail: samori@unistra.fr
Web: http://www.nanochemistry.fr

^b Research Group of Supramolecular and Nanostructured Materials of the Hungarian Academy of Sciences, Dóm tér 8, 6720 Szeged, Hungary

^c University of Szeged, Department of Medicinal Chemistry, Dóm tér 8, 6720 Szeged, Hungary
E-mail: kovacs.lajos@med.u-szeged.hu

^d Alma Mater Studiorum – Università di Bologna, Dipartimento di Chimica “G. Ciamician”, Via San Giacomo 11, 40126 Bologna, Italy

^e Department of Theoretical Chemistry and Amsterdam Center for Multiscale Modeling (ACMM), VU University Amsterdam, De Boelelaan 1083, NL-1081 HV Amsterdam, The Netherlands

^f Institute for Molecules and Materials, Radboud University Nijmegen, Heyendaalseweg 135, NL-6525 AJ Nijmegen, The Netherlands

Abstract

The control over the formation of a bi-component porous network was attained by the self-assembly at a solid–liquid interface by exploiting both primary and secondary non-covalent interactions between melamine and N³-alkylated xanthine modules.

This article is part of the themed collection: Scanning tunneling microscopy: revealing new physical chemistry insight

Physical Chemistry Chemical Physics

Supramolecular H-bonded porous networks at surfaces: exploiting primary and secondary interactions in a bi-component melamine–xanthine system†‡

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