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Issue 45, 2013
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Syntheses of two imidazolate-4-amide-5-imidate linker-based hexagonal metal–organic frameworks with flexible ethoxy substituent

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Abstract

A rare example of in situ linker generation with the formation of soft porous Zn- and Co-MOFs (IFP-9 and -10, respectively) is reported. The flexible ethoxy groups of IFP-9 and -10 protrude into the 1D hexagonal channels. The gas-sorption behavior of both materials for H2, CO2 and CH4 showed wide hysteretic isotherms, typical for MOFs having a flexible substituent which can give rise to a gate effect.

Graphical abstract: Syntheses of two imidazolate-4-amide-5-imidate linker-based hexagonal metal–organic frameworks with flexible ethoxy substituent

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Publication details

The article was received on 16 Aug 2013, accepted on 08 Oct 2013 and first published on 08 Oct 2013


Article type: Communication
DOI: 10.1039/C3CE41632A
Citation: CrystEngComm, 2013,15, 9394-9399
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    Syntheses of two imidazolate-4-amide-5-imidate linker-based hexagonal metal–organic frameworks with flexible ethoxy substituent

    S. S. Mondal, S. Dey, I. A. Baburin, A. Kelling, U. Schilde, G. Seifert, C. Janiak and H. Holdt, CrystEngComm, 2013, 15, 9394
    DOI: 10.1039/C3CE41632A

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