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Issue 45, 2013

Correlating structure and chemistry through simultaneous in situ pair distribution function and infrared spectroscopy measurements

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Abstract

Desorption of coordinated and non-coordinated guests from the nanoporous Prussian blue analogue MnII3[CoIII(CN)6]2(H2O)6x{H2O} was probed by simultaneous pair distribution function and infrared spectroscopy measurements. The combined data shows how the release of guests from different sites is coupled to structural relaxation of the framework.

Graphical abstract: Correlating structure and chemistry through simultaneous in situ pair distribution function and infrared spectroscopy measurements

Article information


Submitted
23 Jul 2013
Accepted
29 Aug 2013
First published
03 Sep 2013

CrystEngComm, 2013,15, 9377-9381
Article type
Communication

Correlating structure and chemistry through simultaneous in situ pair distribution function and infrared spectroscopy measurements

K. W. Chapman, K. A. Beyer, H. Zhao and P. J. Chupas, CrystEngComm, 2013, 15, 9377 DOI: 10.1039/C3CE41458B

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