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Issue 45, 2013
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Alternative synthetic methodology for amide formation in the post-synthetic modification of Ti-MIL125-NH2

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Abstract

There are relatively few metal–organic framework materials that are robust enough to survive post-synthetic modification of their structures. We present test modifications of Ti-MIL125-NH2 leading towards tuning of the porous and catalytic properties of the material. We also present the first use of a mild amide synthesis method for post-synthetic modification.

Graphical abstract: Alternative synthetic methodology for amide formation in the post-synthetic modification of Ti-MIL125-NH2

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Supplementary files

Article information


Submitted
07 Jul 2013
Accepted
30 Aug 2013
First published
02 Sep 2013

CrystEngComm, 2013,15, 9368-9371
Article type
Communication

Alternative synthetic methodology for amide formation in the post-synthetic modification of Ti-MIL125-NH2

A. P. Smalley, D. G. Reid, J. C. Tan and G. O. Lloyd, CrystEngComm, 2013, 15, 9368 DOI: 10.1039/C3CE41332B

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