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Issue 45, 2013

[2 + 2] Cycloaddition reaction as a tool to monitor the formation of thermodynamically stable ladder coordination polymers

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Abstract

A linear Cu(II) coordination polymer was transformed to a sheet or ladder structure by the loss of coordinated DMF when the single crystals or the ground powder, respectively, were used. Further, the sheet structure rearranged to a ladder polymer when the desolvated single crystals were ground to powder, as monitored by 1H-NMR spectroscopy.

Graphical abstract: [2 + 2] Cycloaddition reaction as a tool to monitor the formation of thermodynamically stable ladder coordination polymers

Supplementary files

Article information


Submitted
19 Jun 2013
Accepted
26 Jul 2013
First published
16 Aug 2013

CrystEngComm, 2013,15, 9324-9327
Article type
Communication

[2 + 2] Cycloaddition reaction as a tool to monitor the formation of thermodynamically stable ladder coordination polymers

A. Chanthapally, W. T. Oh and J. J. Vittal, CrystEngComm, 2013, 15, 9324 DOI: 10.1039/C3CE41176A

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