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Issue 45, 2013

Encapsulation of polyoxometalates within layered metal–organic frameworks with topological and pore control

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Abstract

Organic links of varied structure metrics and functionalities connect with Cu2(COO)4 clusters to afford layered metal–organic frameworks. Through topological and pore control, polyoxometalates could be synthetically encapsulated within the cavities. The templating effects of polyoxometalates and specific link functionalizations provide two strategies for controllably incorporating these active species into frameworks.

Graphical abstract: Encapsulation of polyoxometalates within layered metal–organic frameworks with topological and pore control

Supplementary files

Article information


Submitted
13 Jun 2013
Accepted
29 Jul 2013
First published
28 Aug 2013

CrystEngComm, 2013,15, 9340-9343
Article type
Communication

Encapsulation of polyoxometalates within layered metal–organic frameworks with topological and pore control

Z. He, Q. Pang, D. Rankine, C. J. Sumby, L. Zhang, C. J. Doonan and Q. Li, CrystEngComm, 2013, 15, 9340 DOI: 10.1039/C3CE41136B

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