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Issue 45, 2013

A highly porous agw-type metal–organic framework and its CO2 and H2adsorption capacity

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Abstract

An unsymmetrical tricarboxylate ligand with linking alkyne moiety has been used to construct a highly porous metal–organic framework with agw topology. The obtained Cu(II) MOF exhibits a high BET surface area of 3337.0 m2 g−1, a large capacity of CO2 (21.2 mmol g−1 at 298 K and 20 bar) and a good H2 adsorption (5.8 wt% at 77 K and 20 bar).

Graphical abstract: A highly porous agw-type metal–organic framework and its CO2 and H2 adsorption capacity

Supplementary files

Article information


Submitted
12 Jun 2013
Accepted
14 Aug 2013
First published
15 Aug 2013

CrystEngComm, 2013,15, 9348-9351
Article type
Communication

A highly porous agw-type metal–organic framework and its CO2 and H2 adsorption capacity

Z. Lu, L. Du, B. Zheng, J. Bai, M. Zhang and R. Yun, CrystEngComm, 2013, 15, 9348 DOI: 10.1039/C3CE41119B

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