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Issue 45, 2013

Morphological diversity of Mn(iii) metalloporphyrin-based nano- and microsized CPAs assembled via kinetic and thermodynamic controls and their application in heterogeneous catalysis

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Abstract

A series of narrowly dispersed nano- and microsized CPAs has been prepared from a (porphyrin)Mn(III) biscarboxylic acid and Co(OAc)2. The morphologies have been diversified from amorphous spheres to crystalline cubes by varying reaction periods. In addition, their heterogeneous catalytic olefin oxidations are successfully demonstrated.

Graphical abstract: Morphological diversity of Mn(iii) metalloporphyrin-based nano- and microsized CPAs assembled via kinetic and thermodynamic controls and their application in heterogeneous catalysis

Supplementary files

Article information


Submitted
09 Jun 2013
Accepted
24 Aug 2013
First published
29 Aug 2013

CrystEngComm, 2013,15, 9360-9363
Article type
Communication

Morphological diversity of Mn(III) metalloporphyrin-based nano- and microsized CPAs assembled via kinetic and thermodynamic controls and their application in heterogeneous catalysis

K. Y. Lee, Y. S. Lee, S. Kim, H. M. Ha, S. Bae, S. Huh, H. G. Jang and S. J. Lee, CrystEngComm, 2013, 15, 9360 DOI: 10.1039/C3CE41072B

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