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Issue 45, 2013

A mesoporous lanthanide–organic framework constructed from a dendritic hexacarboxylate with cages of 2.4 nm

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Abstract

Solvothermal reaction of a dendritic hexacarboxylic acid with Tb(NO3)3·6H2O afforded a mesoporous lanthanide–organic framework (UTSA-61) whose single-crystal X-ray structure was characterized to have octahedral cages of 2.4 nm in diameter. This mesoporous MOF not only exhibits novel hey topology, but also maintains permanent porosity as shown in its N2, H2, CO2 and CH4 gas sorption isotherms.

Graphical abstract: A mesoporous lanthanide–organic framework constructed from a dendritic hexacarboxylate with cages of 2.4 nm

Supplementary files

Article information


Submitted
08 Jun 2013
Accepted
29 Jul 2013
First published
31 Jul 2013

CrystEngComm, 2013,15, 9328-9331
Article type
Communication

A mesoporous lanthanide–organic framework constructed from a dendritic hexacarboxylate with cages of 2.4 nm

Y. He, H. Furukawa, C. Wu, M. O'Keeffe and B. Chen, CrystEngComm, 2013, 15, 9328 DOI: 10.1039/C3CE41062E

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