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Issue 45, 2013

A supramolecular dual-host based ion-pair induced formation of 1D coordination polymer

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Abstract

An N-bridged tripodal urea receptor (L1) in combination with 18-crown-6-ether (LC) has been structurally authenticated to self-assemble into an integrated 1D coordination polymer in the presence of potassium carbonate (K2CO3). The tripodal receptor (L1) encapsulates a carbonate anion within a dimeric capsular assembly. A carbonyl group and a nitro group from each tripodal unit of the dimeric assembly are coordinated to each crown ether bound potassium ion, generating a 1D coordination polymer. Thus, an anion-pair induced 1D integrated polymeric assembly is formed based on two hosts in combination.

Graphical abstract: A supramolecular dual-host based ion-pair induced formation of 1D coordination polymer

Supplementary files

Article information


Submitted
07 Jun 2013
Accepted
12 Aug 2013
First published
12 Aug 2013

CrystEngComm, 2013,15, 9641-9647
Article type
Paper

A supramolecular dual-host based ion-pair induced formation of 1D coordination polymer

R. Chutia, S. K. Dey and G. Das, CrystEngComm, 2013, 15, 9641 DOI: 10.1039/C3CE41054D

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