Issue 45, 2013
From the journal:

CrystEngComm

Self-assembly of a chiral three-dimensional manganese(ii)–copper(ii) coordination polymer with a double helical architecture†

Thais Grancha,a   Clarisse Tourbillon,‡a   Jesús Ferrando-Soria,*b   Miguel Julve,a   Francesc Lloret,a   Jorge Pasán,c   Catalina Ruiz-Pérez,c   Oscar Fabelocd  and  Emilio Pardo*a  

* Corresponding authors

a Departament de Química Inorgànica, Instituto de Ciencia Molecular (ICMOL). Universitat de València, 46980 Paterna, València, Spain
E-mail: Emilio.Pardo@uv.es
Fax: +343543273
Tel: +343544442

b Department of Chemistry, Texas A&M University College Station, TX 77843, USA
E-mail: jesus.ferrando@chem.tamu.edu

c Laboratorio de Rayos X y Materiales Moleculares, Depto. de Fisica Fundamental II. Universidad de La Laguna, 38201 Tenerife, Spain

d Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza, Zaragoza, Spain

Abstract

The use of the anionic dicopper(II) complex, [CuII(mpba)2]4− [mpba = N,N′-1,3-phenylenebis(oxamate)], as tetrakis(bidentate) metalloligand toward MnII ions in the presence of oxalate and the chiral (S)-trimethyl-(1-phenylethyl)ammonium cation affords the first example of a mixed oxalato/oxamato-based chiral 3D metal–organic polymer.

Graphical abstract: Self-assembly of a chiral three-dimensional manganese(ii)–copper(ii) coordination polymer with a double helical architecture

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Article information

DOI
https://doi.org/10.1039/C3CE41022F
Article type
Communication
Submitted
05 Jun 2013
Accepted
08 Jul 2013
First published
08 Jul 2013

CrystEngComm, 2013,15, 9312-9315

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Self-assembly of a chiral three-dimensional manganese(II)–copper(II) coordination polymer with a double helical architecture

T. Grancha, C. Tourbillon, J. Ferrando-Soria, M. Julve, F. Lloret, J. Pasán, C. Ruiz-Pérez, O. Fabelo and E. Pardo, CrystEngComm, 2013, 15, 9312 DOI: 10.1039/C3CE41022F

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