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Issue 45, 2013

Self-assembly of a chiral three-dimensional manganese(ii)–copper(ii) coordination polymer with a double helical architecture

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Abstract

The use of the anionic dicopper(II) complex, [CuII(mpba)2]4− [mpba = N,N′-1,3-phenylenebis(oxamate)], as tetrakis(bidentate) metalloligand toward MnII ions in the presence of oxalate and the chiral (S)-trimethyl-(1-phenylethyl)ammonium cation affords the first example of a mixed oxalato/oxamato-based chiral 3D metal–organic polymer.

Graphical abstract: Self-assembly of a chiral three-dimensional manganese(ii)–copper(ii) coordination polymer with a double helical architecture

Supplementary files

Article information


Submitted
05 Jun 2013
Accepted
08 Jul 2013
First published
08 Jul 2013

CrystEngComm, 2013,15, 9312-9315
Article type
Communication

Self-assembly of a chiral three-dimensional manganese(II)–copper(II) coordination polymer with a double helical architecture

T. Grancha, C. Tourbillon, J. Ferrando-Soria, M. Julve, F. Lloret, J. Pasán, C. Ruiz-Pérez, O. Fabelo and E. Pardo, CrystEngComm, 2013, 15, 9312 DOI: 10.1039/C3CE41022F

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