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Issue 44, 2013
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A new synthetic approach to force bond formation between a transition metal complex and a thiostannate anion: solvothermal synthesis and crystal structure of [Co2(cyclam)2Sn2S6]·2H2O

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Abstract

Applying a new synthetic approach using [Co(cyclam)Cl2]Cl as educt afforded crystallization of the layered compound [Co2(cyclam)2Sn2S6]·2H2O by replacement of the axial Cl ions in the complex by Co–S bonds to the in situ generated [Sn2S6]4− anion.

Graphical abstract: A new synthetic approach to force bond formation between a transition metal complex and a thiostannate anion: solvothermal synthesis and crystal structure of [Co2(cyclam)2Sn2S6]·2H2O

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Article information


Submitted
31 May 2013
Accepted
30 Aug 2013
First published
06 Sep 2013

CrystEngComm, 2013,15, 8874-8876
Article type
Communication

A new synthetic approach to force bond formation between a transition metal complex and a thiostannate anion: solvothermal synthesis and crystal structure of [Co2(cyclam)2Sn2S6]·2H2O

C. Zeisler, C. Näther and W. Bensch, CrystEngComm, 2013, 15, 8874
DOI: 10.1039/C3CE40976G

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