Anion-selectivity of cationic cluster–organic nanospheres based on a nest-shaped [MS4Cu3X3] clustermonomer with a ditopic ligand

Ling Qin; Zhaorui Pan; Liwu Qian; Yizhi Li; Zijian Guo; Hegen Zheng

doi:10.1039/C3CE40542G

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Anion-selectivity of cationic cluster–organic nanospheres based on a nest-shaped [MS₄Cu₃X₃] clustermonomer with a ditopic ligand†

Ling Qin,^a Zhaorui Pan,^a Liwu Qian,^a Yizhi Li,^a Zijian Guo^a and Hegen Zheng*^a

Author affiliations

* Corresponding authors

^a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, National Laboratory of Microstructures, Nanjing University, Nanjing 210093, P. R. China
E-mail: zhenghg@nju.edu.cn
Fax: +86-25-83314502

Abstract

Three heterothiometallic cluster–organic nanospheres have been synthesized and characterized. They own identical cationic cluster–organic nanoball frameworks and show selectivity towards charge-balancing anions. It is also interesting that the morphology of the as-prepared particles can be tuned by simply varying the polarity of the solvent.

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Article information

DOI: https://doi.org/10.1039/C3CE40542G
Article type: Communication
Submitted: 27 Mar 2013
Accepted: 18 Apr 2013
First published: 19 Apr 2013

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CrystEngComm, 2013,15, 5016-5019

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Anion-selectivity of cationic cluster–organic nanospheres based on a nest-shaped [MS₄Cu₃X₃] clustermonomer with a ditopic ligand

L. Qin, Z. Pan, L. Qian, Y. Li, Z. Guo and H. Zheng, CrystEngComm, 2013, 15, 5016 DOI: 10.1039/C3CE40542G

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