Issue 25, 2013
From the journal:

CrystEngComm

[AEPH2][GeSb2S6]·CH3OH: a thiogermanate–thioantimonate featuring an infinite ribbon-like structure with an unusual {GeSb3S11} unit and exhibiting the ability of photocatalytic degradation of organic dye†

Mei-Ling Feng,a   Chun-Li Hu,a   Kai-Yao Wang,a   Cheng-Feng Dua  and  Xiao-Ying Huang*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China
E-mail: xyhuang@fjirsm.ac.cn
Fax: +86 591 83793727

Abstract

A new thiogermanate–thioantimonate, namely, [AEPH2][GeSb2S6]·CH3OH (1) (AEP = N-(2-aminoethyl)piperazine) has been solvothermally synthesized, whose structure features a one-dimensional anionic ribbon of [GeSb2S6]n2n− built of the firstly observed tetranuclear {GeSb3S11} cluster as secondary building unit. The photocatalytic study indicated that 1 was able to degrade Rhodamine B under visible irradiation.

Graphical abstract: [AEPH2][GeSb2S6]·CH3OH: a thiogermanate–thioantimonate featuring an infinite ribbon-like structure with an unusual {GeSb3S11} unit and exhibiting the ability of photocatalytic degradation of organic dye

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Article information

DOI
https://doi.org/10.1039/C3CE40143J
Article type
Communication
Submitted
23 Jan 2013
Accepted
28 Apr 2013
First published
30 Apr 2013

CrystEngComm, 2013,15, 5007-5011

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[AEPH2][GeSb2S6]·CH3OH: a thiogermanate–thioantimonate featuring an infinite ribbon-like structure with an unusual {GeSb3S11} unit and exhibiting the ability of photocatalytic degradation of organic dye

M. Feng, C. Hu, K. Wang, C. Du and X. Huang, CrystEngComm, 2013, 15, 5007 DOI: 10.1039/C3CE40143J

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