Issue 11, 2013
From the journal:

CrystEngComm

Side functionalization of diboronic acid precursors for covalent organic frameworks†

Thomas Faury,ab   Frédéric Dumur,*b   Sylvain Clair,*a   Mathieu Abel,a   Louis Portea  and  Didier Gigmesb  

* Corresponding authors

a CNRS, ICR, UMR 7273, Aix-Marseille University, F-13397 Marseille Cedex 20, France
E-mail: frederic.dumur@univ-amu.fr
Fax: +33 4 91 28 87 58
Tel: +33 4 91 28 27 48

b CNRS, IM2NP, UMR 7334, Aix-Marseille University, F-13397 Marseille Cedex 20, France
E-mail: sylvain.clair@univ-amu.fr
Tel: +33 4 91 28 85 38

Abstract

A series of substituted 1,4-benzenediboronic acids (BDBA) was synthesized and their thermal properties investigated. Two diboronic acids were studied as building-blocks for covalent organic framework (COF) formation, namely 2,5-dimethoxy-1,4-benzenediboronic acid and 2-nitro-1,4-benzeneboronic acid. Interestingly, substitution of the BDBA core caused a dramatic decrease of the polymerization temperature leading to the formation of a less organized structure.

Graphical abstract: Side functionalization of diboronic acid precursors for covalent organic frameworks

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Article information

DOI
https://doi.org/10.1039/C3CE26494G
Article type
Paper
Submitted
14 Sep 2012
Accepted
24 Jan 2013
First published
24 Jan 2013

CrystEngComm, 2013,15, 2067-2075

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Side functionalization of diboronic acid precursors for covalent organic frameworks

T. Faury, F. Dumur, S. Clair, M. Abel, L. Porte and D. Gigmes, CrystEngComm, 2013, 15, 2067 DOI: 10.1039/C3CE26494G

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