Targeted synthesis of a mesoporous triptycene-derived covalent organic framework

Zafer Kahveci; Timur Islamoglu; Ghulam Abbas Shar; Ransheng Ding; Hani M. El-Kaderi

doi:10.1039/C2CE26487K

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Targeted synthesis of a mesoporous triptycene-derived covalent organic framework†

Zafer Kahveci,^a Timur Islamoglu,^a Ghulam Abbas Shar,^a Ransheng Ding^a and Hani M. El-Kaderi*^a

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* Corresponding authors

^a Department of Chemistry, Virginia Commonwealth University, Richmond, VA 23284-2006, USA
E-mail: helkaderi@vcu.edu
Fax: +1 804 828 8599
Tel: +1 804 828 7505

Abstract

The synthesis and characterization of a highly porous triptycene-derived covalent organic framework (TDCOF-5) and its performance in small gas storage are reported. TDCOF-5 crystallizes into a 2D mesoporous network that contains accessible boron sites, exhibits high surface area (SA_Lang = 3832 m² g⁻¹), and high gas uptake under low pressure settings.

This article is part of the themed collection: Covalent organic frameworks

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Article information

DOI: https://doi.org/10.1039/C2CE26487K
Article type: Communication
Submitted: 13 Sep 2012
Accepted: 08 Nov 2012
First published: 08 Nov 2012

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CrystEngComm, 2013,15, 1524-1527

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Targeted synthesis of a mesoporous triptycene-derived covalent organic framework

Z. Kahveci, T. Islamoglu, G. A. Shar, R. Ding and H. M. El-Kaderi, CrystEngComm, 2013, 15, 1524 DOI: 10.1039/C2CE26487K

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CrystEngComm

Targeted synthesis of a mesoporous triptycene-derived covalent organic framework†

Abstract

Supplementary files

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Targeted synthesis of a mesoporous triptycene-derived covalent organic framework

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