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Issue 91, 2013
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Synthesis, characterisation, and oxygen atom transfer reactions involving the first gold(i)-alkylperoxo complexes

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Abstract

The synthesis of a new class of organogold species containing a peroxo moiety is reported. Complexes [Au(IPr)(OOtBu)] and [Au(SIPr)(OOtBu)] have been synthesised via a straightforward methodology using the parent gold(I) hydroxide complexes as synthons. These complexes have been successfully used in oxygen-transfer reactions to triphenylphosphine.

Graphical abstract: Synthesis, characterisation, and oxygen atom transfer reactions involving the first gold(i)-alkylperoxo complexes

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Article information


Submitted
13 Sep 2013
Accepted
27 Sep 2013
First published
30 Sep 2013

Chem. Commun., 2013,49, 10745-10747
Article type
Communication

Synthesis, characterisation, and oxygen atom transfer reactions involving the first gold(I)-alkylperoxo complexes

A. Collado, A. Gómez-Suárez, Y. Oonishi, A. M. Z. Slawin and S. P. Nolan, Chem. Commun., 2013, 49, 10745
DOI: 10.1039/C3CC47030J

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