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Herein, we report experimental and computational results for the carboxylation of abnormal anionic N-heterocyclic dicarbenes (NHDCs) with CO2. Under ambient dosing conditions, carbonyl addition occurs selectively at C4 without a second carboxylation event occurring at the C2 carbene center.

Graphical abstract: Site specific carboxylation of abnormal anionic N-heterocyclic dicarbenes with CO2

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