Issue 93, 2013
From the journal:

Chemical Communications

Copper-catalyzed Csp2–H amidation of unactivated arenes by N-tosyloxycarbamates†

Alex John,a   Jeena Byuna  and  Kenneth M. Nicholas*a  

* Corresponding authors

a Department of Chemistry & Biochemistry, Stephenson Life Sciences Research Center, Univ. of Oklahoma, Norman, Oklahoma–73019, USA
E-mail: knicholas@ou.edu
Fax: +1-405-325-6111

Abstract

[(Neocuproine)Cu]PF6 catalyzes the C–H amidation of unactivated arenes by N-tosyloxytrichloroethylcarbamates. Alkyl benzenes are selectively converted to aromatic amines and substituted arenes display variable regioselectivity.

Graphical abstract: Copper-catalyzed Csp2–H amidation of unactivated arenes by N-tosyloxycarbamates

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Article information

DOI
https://doi.org/10.1039/C3CC46412A
Article type
Communication
Submitted
21 Aug 2013
Accepted
10 Oct 2013
First published
17 Oct 2013

Chem. Commun., 2013,49, 10965-10967

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Copper-catalyzed Csp2–H amidation of unactivated arenes by N-tosyloxycarbamates

A. John, J. Byun and K. M. Nicholas, Chem. Commun., 2013, 49, 10965 DOI: 10.1039/C3CC46412A

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