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Issue 89, 2013
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Probing secondary coordination sphere influence on the oxygenation of zinc alkyls: formation of a unique zinc peroxide species

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Abstract

Reactions of ethylzinc derivatives of o-hydroxybiphenyl with O2 were investigated. The study revealed an essential role in the oxygenation process of intra-molecular interactions involving aromatic rings and provided a unique aryloxide (hydroxide) Zn8(OAr)8(OH)6(O2) cluster with an encapsulated peroxide species.

Graphical abstract: Probing secondary coordination sphere influence on the oxygenation of zinc alkyls: formation of a unique zinc peroxide species

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Article information


Submitted
13 Aug 2013
Accepted
17 Sep 2013
First published
17 Sep 2013

Chem. Commun., 2013,49, 10477-10479
Article type
Communication

Probing secondary coordination sphere influence on the oxygenation of zinc alkyls: formation of a unique zinc peroxide species

P. Sobota, R. Petrus, K. Zelga, Ł. Mąkolski, D. Kubicki and J. Lewiński, Chem. Commun., 2013, 49, 10477
DOI: 10.1039/C3CC46206D

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