A C3v-symmetrical tribenzotriquinacene-based threefold N-heterocyclic carbene. Coordination to rhodium(I) and stereoelectronic properties

Candela Segarra; Jens Linke; Elena Mas-Marzá; Dietmar Kuck; Eduardo Peris

doi:10.1039/C3CC46155F

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A C_3v-symmetrical tribenzotriquinacene-based threefold N-heterocyclic carbene. Coordination to rhodium(i) and stereoelectronic properties†

Candela Segarra,^a Jens Linke,^b Elena Mas-Marzá,^c Dietmar Kuck*^b and Eduardo Peris*^a

Author affiliations

* Corresponding authors

^a Dpt. de Química Inorgánica y Orgánica, Universitat Jaume I, Av. Vicente Sos Baynat s/n, 12071-Castellón, Spain
E-mail: eperis@uji.es
Fax: +34 964 387522

^b Department of Chemistry, Bielefeld University, Universitätsstraβe 25, 33615 Bielefeld, Germany
E-mail: dietmar.kuck@uni-bielefeld.de
Fax: +49 5211066146
Tel: +49 5211062060

^c Departamento de Química Orgánica, Universidad de Sevilla, C/ Profesor García González, s/n, Sevilla, Spain

Abstract

A novel tribenzotriquinacene-based tris-NHC has been obtained and coordinated to rhodium. The new ligand displays a unique rigid C_3v symmetry. The electrochemical analysis of the tri-rhodium complex reveals that the three metals are essentially disconnected.

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Article information

DOI: https://doi.org/10.1039/C3CC46155F
Article type: Communication
Submitted: 12 Aug 2013
Accepted: 18 Sep 2013
First published: 19 Sep 2013

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Chem. Commun., 2013,49, 10572-10574

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A C_3v-symmetrical tribenzotriquinacene-based threefold N-heterocyclic carbene. Coordination to rhodium(I) and stereoelectronic properties

C. Segarra, J. Linke, E. Mas-Marzá, D. Kuck and E. Peris, Chem. Commun., 2013, 49, 10572 DOI: 10.1039/C3CC46155F

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