Issue 92, 2013
From the journal:

Chemical Communications

Oxidative 1,2-difunctionalization of activated alkenes with benzylic C(sp3)–H bonds and aryl C(sp2)–H bonds†

Ming-Bo Zhou,a   Cheng-Yong Wang,a   Ren-Jie Song,a   Yu Liu,a   Wen-Ting Weia  and  Jin-Heng Li*a  

* Corresponding authors

a State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China
E-mail: jhli@hnu.edu.cn
Fax: +86 731 8871 3642
Tel: +86 731 8882 2286

Abstract

DTBP (di-tert-butyl peroxide) is utilized to mediate oxidative 1,2-difunctionalization of activated alkenes with an aryl C(sp2)–H bond and a benzylic C(sp3)–H bond for the synthesis of functionalized oxindoles. This reaction is a new organomediated strategy for alkene difunctionalization facilitated by Lewis acids.

Graphical abstract: Oxidative 1,2-difunctionalization of activated alkenes with benzylic C(sp3)–H bonds and aryl C(sp2)–H bonds

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Article information

DOI
https://doi.org/10.1039/C3CC45861J
Article type
Communication
Submitted
31 Jul 2013
Accepted
30 Aug 2013
First published
30 Aug 2013

Chem. Commun., 2013,49, 10817-10819

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Oxidative 1,2-difunctionalization of activated alkenes with benzylic C(sp3)–H bonds and aryl C(sp2)–H bonds

M. Zhou, C. Wang, R. Song, Y. Liu, W. Wei and J. Li, Chem. Commun., 2013, 49, 10817 DOI: 10.1039/C3CC45861J

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