Temperature, light and solvent-induced spin transition in a 3D 2-fold interpenetrated PtS-type porous coordination polymer†
Abstract
A 3D 2-fold interpenetrated porous coordination polymer, [Fe(NCS)2(tppm)]·5CH3OH·2CH2Cl2 (1·sol, tppm = 4,4′,4′′,4′′′-tetrakis(4-pyridylethen-2-yl)tetraphenylmethane), was synthesized, which showed temperature, light and solvent-induced spin-crossover behaviours.