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Issue 84, 2013
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A redox-triggered structural rearrangement in an iodate-templated polyoxotungstate cluster cage

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Abstract

The new tungstatoiodate, α-[H5W18O59(IO3)]6−, containing IVO3 within a {W18O54} metal oxide framework has been prepared and shown by X-ray crystallography and mass spectrometry to be derived from the fully oxidised [H3W18O56(IO6)]6− by two-electron reduction accompanied by a redox-triggered structural rearrangement where three I–O covalent bonds are broken.

Graphical abstract: A redox-triggered structural rearrangement in an iodate-templated polyoxotungstate cluster cage

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Article information


Submitted
25 Jul 2013
Accepted
30 Aug 2013
First published
02 Sep 2013

Chem. Commun., 2013,49, 9731-9733
Article type
Communication

A redox-triggered structural rearrangement in an iodate-templated polyoxotungstate cluster cage

D. Long, J. Yan, A. Ruiz de la Oliva, C. Busche, H. N. Miras, R. J. Errington and L. Cronin, Chem. Commun., 2013, 49, 9731
DOI: 10.1039/C3CC45659E

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