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Issue 85, 2013
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σ-Coordination of metal–boryl bonds to gold(i)

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The first examples of σ-coordinated metal–haloboryl complexes have been synthesised. The haloboryl moiety may be functionalized by nucleophilic substitution reactions, by which more electron-withdrawing substituents may be installed at the boron center.

Graphical abstract: σ-Coordination of metal–boryl bonds to gold(i)

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Article information

18 Jul 2013
15 Aug 2013
First published
15 Aug 2013

Chem. Commun., 2013,49, 9905-9907
Article type

σ-Coordination of metal–boryl bonds to gold(I)

H. Braunschweig, K. Radacki and R. Shang, Chem. Commun., 2013, 49, 9905
DOI: 10.1039/C3CC45455J

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