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Issue 85, 2013
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σ-Coordination of metal–boryl bonds to gold(I)

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The first examples of σ-coordinated metal–haloboryl complexes have been synthesised. The haloboryl moiety may be functionalized by nucleophilic substitution reactions, by which more electron-withdrawing substituents may be installed at the boron center.

Graphical abstract: σ-Coordination of metal–boryl bonds to gold(i)

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The article was received on 18 Jul 2013, accepted on 15 Aug 2013 and first published on 15 Aug 2013

Article type: Communication
DOI: 10.1039/C3CC45455J
Citation: Chem. Commun., 2013,49, 9905-9907
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    σ-Coordination of metal–boryl bonds to gold(I)

    H. Braunschweig, K. Radacki and R. Shang, Chem. Commun., 2013, 49, 9905
    DOI: 10.1039/C3CC45455J

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