Issue 80, 2013
From the journal:

Chemical Communications

Stereoselective synthesis, structural aspects, and NMR properties of stable C-fluorinated phosphaalkenes†

Shigekazu Ito,*a   Takeshi Nakagawaa  and  Koichi Mikamia  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro, Tokyo 152-8552, Japan
E-mail: ito.s.ao@m.titech.ac.jp
Fax: +81 3 5734 2143

Abstract

We report a stereoselective route to synthesize (E)-2-bromo-2-fluoro-1-(2,4,6-tri-t-butylphenyl)-2-phosphaethene. Configurationally and conformationally controlled 2-fluoro-1-phosphaethene [Mes*P[double bond, length as m-dash]C(F)H; Mes* = 2,4,6-tBu3C6H2] and 2-fluoro-1,3-diphosphapropene [Mes*P[double bond, length as m-dash]C(F)-PPh2] were synthesized and the NMR data, including relaxation parameters, were collected.

Graphical abstract: Stereoselective synthesis, structural aspects, and NMR properties of stable C-fluorinated phosphaalkenes

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Article information

DOI
https://doi.org/10.1039/C3CC45237A
Article type
Communication
Submitted
11 Jul 2013
Accepted
08 Aug 2013
First published
08 Aug 2013

Chem. Commun., 2013,49, 9221-9223

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Stereoselective synthesis, structural aspects, and NMR properties of stable C-fluorinated phosphaalkenes

S. Ito, T. Nakagawa and K. Mikami, Chem. Commun., 2013, 49, 9221 DOI: 10.1039/C3CC45237A

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