Issue 77, 2013
From the journal:

Chemical Communications

Developing catalytic applications of cooperative bimetallics: competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates†

Alberto Hernán-Gómez,a   Tyne D. Bradley,a   Alan R. Kennedy,a   Zoe Livingstone,a   Stuart D. Robertsona  and  Eva Hevia*a  

* Corresponding authors

a WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, UK
E-mail: eva.hevia@strath.ac.uk

Abstract

Mixed-metal reagents [NaMg(CH2SiMe3)3] (1) and [(THF)NaMg(NPh2)3(THF)] [3-(THF)2] can act as precatalysts to selectively promote the hydroamination/trimerization of isocyanates (RNCO) depending on the steric bulk of the R substituent.

Graphical abstract: Developing catalytic applications of cooperative bimetallics: competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates

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Article information

DOI
https://doi.org/10.1039/C3CC45167D
Article type
Communication
Submitted
09 Jul 2013
Accepted
20 Jul 2013
First published
22 Jul 2013

Chem. Commun., 2013,49, 8659-8661

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Developing catalytic applications of cooperative bimetallics: competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates

A. Hernán-Gómez, T. D. Bradley, A. R. Kennedy, Z. Livingstone, S. D. Robertson and E. Hevia, Chem. Commun., 2013, 49, 8659 DOI: 10.1039/C3CC45167D

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