Issue 78, 2013
From the journal:

Chemical Communications

Reductive amination of tertiary anilines and aldehydes†

Yunhe Lv,a   Yiying Zheng,a   Yan Li,*a   Tao Xiong,a   Jingping Zhang,a   Qun Liua  and  Qian Zhang*a  

* Corresponding authors

a Department of Chemistry, Northeast Normal University, Changchun, China
E-mail: liy078@nenu.edu.cn, zhangq651@nenu.edu.cn
Fax: +86-431-5099759

Abstract

An unprecedented oxidant-mediated reductive amination of tertiary anilines and aldehydes without external reducing agents was developed via the nucleophilic attack of the oxygen atom of the carbonyl group to in situ generated iminium ions, in which tertiary anilines were used as both nitrogen source and reducing agent for the first time.

Graphical abstract: Reductive amination of tertiary anilines and aldehydes

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Article information

DOI
https://doi.org/10.1039/C3CC45084H
Article type
Communication
Submitted
06 Jul 2013
Accepted
01 Aug 2013
First published
21 Aug 2013

Chem. Commun., 2013,49, 8866-8868

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Reductive amination of tertiary anilines and aldehydes

Y. Lv, Y. Zheng, Y. Li, T. Xiong, J. Zhang, Q. Liu and Q. Zhang, Chem. Commun., 2013, 49, 8866 DOI: 10.1039/C3CC45084H

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