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Issue 79, 2013
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Tetrathiafulvalene-annulated [28]hexaphyrin(1.1.1.1.1.1): a multi-electron donor system subject to conformational control

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Abstract

Tetrathiafulvalenes (TTF)-annulated [28]hexaphyrin affords an electron rich flexible π-conjugated system whose limiting conformations can be controlled through choice of solvents. The conformation-dependent intramolecular charge transfer character, as well as electron reserve capability of the hexakis-TTF annulated hexaphyrin, was analyzed.

Graphical abstract: Tetrathiafulvalene-annulated [28]hexaphyrin(1.1.1.1.1.1): a multi-electron donor system subject to conformational control

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Publication details

The article was received on 02 Jul 2013, accepted on 13 Aug 2013 and first published on 15 Aug 2013


Article type: Communication
DOI: 10.1039/C3CC44934C
Citation: Chem. Commun., 2013,49, 8937-8939
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    Tetrathiafulvalene-annulated [28]hexaphyrin(1.1.1.1.1.1): a multi-electron donor system subject to conformational control

    A. Jana, M. Ishida, K. Cho, S. K. Ghosh, K. Kwak, K. Ohkubo, Y. M. Sung, C. M. Davis, V. M. Lynch, D. Lee, S. Fukuzumi, D. Kim and J. L. Sessler, Chem. Commun., 2013, 49, 8937
    DOI: 10.1039/C3CC44934C

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