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Issue 79, 2013

Tetrathiafulvalene-annulated [28]hexaphyrin(1.1.1.1.1.1): a multi-electron donor system subject to conformational control

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Abstract

Tetrathiafulvalenes (TTF)-annulated [28]hexaphyrin affords an electron rich flexible π-conjugated system whose limiting conformations can be controlled through choice of solvents. The conformation-dependent intramolecular charge transfer character, as well as electron reserve capability of the hexakis-TTF annulated hexaphyrin, was analyzed.

Graphical abstract: Tetrathiafulvalene-annulated [28]hexaphyrin(1.1.1.1.1.1): a multi-electron donor system subject to conformational control

Supplementary files

Article information


Submitted
02 Jul 2013
Accepted
13 Aug 2013
First published
15 Aug 2013

Chem. Commun., 2013,49, 8937-8939
Article type
Communication

Tetrathiafulvalene-annulated [28]hexaphyrin(1.1.1.1.1.1): a multi-electron donor system subject to conformational control

A. Jana, M. Ishida, K. Cho, S. K. Ghosh, K. Kwak, K. Ohkubo, Y. M. Sung, C. M. Davis, V. M. Lynch, D. Lee, S. Fukuzumi, D. Kim and J. L. Sessler, Chem. Commun., 2013, 49, 8937 DOI: 10.1039/C3CC44934C

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