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Issue 83, 2013
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Modelling electric field control of the spin state in the mixed-valence polyoxometalate [GeV14O40]8−

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Abstract

The two-electron reduced mixed-valence polyoxometalate [GeV14O40]8− presents an unusual paramagnetic behaviour as a consequence of the partial trapping of these electrons. The effect of applying an electric field is that of inducing antiferromagnetic coupling between the two delocalized electronic spins.

Graphical abstract: Modelling electric field control of the spin state in the mixed-valence polyoxometalate [GeV14O40]8−

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Publication details

The article was received on 28 Jun 2013, accepted on 23 Aug 2013 and first published on 23 Aug 2013


Article type: Communication
DOI: 10.1039/C3CC44859B
Chem. Commun., 2013,49, 9621-9623

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    Modelling electric field control of the spin state in the mixed-valence polyoxometalate [GeV14O40]8−

    S. Cardona-Serra, J. M. Clemente-Juan, A. Gaita-Ariño, N. Suaud, O. Svoboda and E. Coronado, Chem. Commun., 2013, 49, 9621
    DOI: 10.1039/C3CC44859B

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