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Issue 79, 2013
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Synthesis and properties of boron complexes of [14]triphyrins(2.1.1)

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Abstract

Boron complexes of [14]triphyrins(2.1.1) were prepared from free-base [14]triphyrins(2.1.1) with phenylboron dichloride. The absorption spectrum of the meso-free β-alkyl–triphyrin boron complex in CH2Cl2 showed a broad weak band at around 640 nm assigned to transition from B-phenyl to the triphyrin, while that of the meso-aryl benzotriphyrin boron complex showed only Soret and Q bands.

Graphical abstract: Synthesis and properties of boron complexes of [14]triphyrins(2.1.1)

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Article information


Submitted
26 Jun 2013
Accepted
04 Aug 2013
First published
21 Aug 2013

Chem. Commun., 2013,49, 8955-8957
Article type
Communication

Synthesis and properties of boron complexes of [14]triphyrins(2.1.1)

D. Kuzuhara, Z. Xue, S. Mori, T. Okujima, H. Uno, N. Aratani and H. Yamada, Chem. Commun., 2013, 49, 8955
DOI: 10.1039/C3CC44788J

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