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Issue 84, 2013
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Pillar substitution modulates CO2 affinity in “mmo” topology networks

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Abstract

The use of WO42− instead of CrO42− or MoO42− as an angular pillar in mmo topology nets has afforded two isostructural porous nets of formula [M(bpe)2WO4] (M = Co or Ni, bpe = 1,2-(4-pyridyl)ethene). The Ni variant, WOFOUR-1-Ni, is highly selective towards CO2 thanks to its exceptionally high isosteric heat of adsorption (Qst) of −65.5 kJ mol−1 at zero loading.

Graphical abstract: Pillar substitution modulates CO2 affinity in “mmo” topology networks

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Article information


Submitted
24 Jun 2013
Accepted
04 Sep 2013
First published
05 Sep 2013

Chem. Commun., 2013,49, 9809-9811
Article type
Communication

Pillar substitution modulates CO2 affinity in “mmo” topology networks

M. H. Mohamed, S. K. Elsaidi, T. Pham, K. A. Forrest, B. Tudor, L. Wojtas, B. Space and M. J. Zaworotko, Chem. Commun., 2013, 49, 9809
DOI: 10.1039/C3CC44745F

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