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Issue 85, 2013
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Heterometallic clusters with a new {Re3Mo3S8} core: direct synthesis, properties and DFT calculations

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Abstract

We report the direct facile high-temperature synthesis and investigation of heterometallic rhenium–molybdenum cluster K6[Re3Mo3S8(CN)4(CN)2/2] (1) with a new {Re3Mo3S8} core. Dissolution of polymeric compound 1 resulted in subsequent oxidation and formation of stable 23e paramagnetic anionic cluster complex [Re3Mo3S8(CN)6]6−.

Graphical abstract: Heterometallic clusters with a new {Re3Mo3S8} core: direct synthesis, properties and DFT calculations

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Publication details

The article was received on 20 Jun 2013, accepted on 28 Aug 2013 and first published on 03 Sep 2013


Article type: Communication
DOI: 10.1039/C3CC44643C
Chem. Commun., 2013,49, 10019-10021

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    Heterometallic clusters with a new {Re3Mo3S8} core: direct synthesis, properties and DFT calculations

    Y. M. Gayfulin, N. G. Naumov, M. R. Rizhikov, A. I. Smolentsev, V. A. Nadolinny and Y. V. Mironov, Chem. Commun., 2013, 49, 10019
    DOI: 10.1039/C3CC44643C

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