Jump to main content
Jump to site search

Issue 74, 2013
Previous Article Next Article

Two-step crystal engineering of porous nets from [Cr33-O)(RCO2)6] and [Cu33-Cl)(RNH2)6Cl6] molecular building blocks

Author affiliations

Abstract

Two porous nets have been prepared via a 2-step crystal engineering approach that links decorated trigonal prismatic [Cr33-O)(CO2)6] and [Cu33-Cl)(RNH2)6Cl6] molecular building blocks, MBBs. tp-PMBB-5-acs-1 is a rare example of a rigid acs underlying net whereas tp-PMBB-6-stp-1, an stp underlying net, exhibits free NH2 groups in its channels and a relatively high isosteric heat of adsorption for CO2.

Graphical abstract: Two-step crystal engineering of porous nets from [Cr3(μ3-O)(RCO2)6] and [Cu3(μ3-Cl)(RNH2)6Cl6] molecular building blocks

Back to tab navigation

Supplementary files

Article information


Submitted
01 Jun 2013
Accepted
17 Jul 2013
First published
22 Jul 2013

Chem. Commun., 2013,49, 8154-8156
Article type
Communication

Two-step crystal engineering of porous nets from [Cr33-O)(RCO2)6] and [Cu33-Cl)(RNH2)6Cl6] molecular building blocks

S. K. Elsaidi, M. H. Mohamed, L. Wojtas, A. J. Cairns, M. Eddaoudi and M. J. Zaworotko, Chem. Commun., 2013, 49, 8154
DOI: 10.1039/C3CC44133D

Social activity

Search articles by author

Spotlight

Advertisements