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Issue 72, 2013
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[4+3] Cycloaddition of in situ generated azoalkenes with C,N-cyclic azomethineimines: efficient synthesis of tetrazepine derivatives

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Abstract

An unprecedented [4+3] cycloaddition of in situ generated azoalkenes with C,N-cyclic azomethine imines has been developed without the use of any catalyst, providing an efficient and mild approach to synthesise highly functionalized 1,2,4,5-tetrazepine derivatives in high yields (76–92%).

Graphical abstract: [4+3] Cycloaddition of in situ generated azoalkenes with C,N-cyclic azomethine imines: efficient synthesis of tetrazepine derivatives

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Supplementary files

Article information


Submitted
28 May 2013
Accepted
05 Jul 2013
First published
09 Jul 2013

Chem. Commun., 2013,49, 7905-7907
Article type
Communication

[4+3] Cycloaddition of in situ generated azoalkenes with C,N-cyclic azomethine imines: efficient synthesis of tetrazepine derivatives

X. Hu, J. Chen, S. Gao, B. Feng, L. Lu and W. Xiao, Chem. Commun., 2013, 49, 7905
DOI: 10.1039/C3CC43888K

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